Here you go, very simple, factual, and non debatable:
1. A car's cooling system maximum pressure ALWAYS references ambient pressure. A 20 psi rad cap will vent when the pressure delta between the cooling system and ambient air exceeds 20 psi.
2. Because of #1, the maximum ABSOLUTE pressure of the cooling system will drop at higher altitudes.
3. Because of #2, the boiling temperature of coolant at high altitudes is reduced.
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HAVING SAID THAT... AN EXAMPLE (assuming a rigid cooling system, a safe assumption for this case):
If a Cruze with a 20 psi cap is only reaching 15 psi in its cooling system running at sea level (14.7 psi ambient, 29.7 psi absolute), when it drives up a mountain where ambient pressure is 5 psi LESS than sea level (9.7 psi), the pressure in the cooling system is effectively 20 psi. The absolute pressure has not changed (20 + 9.7 = 29.7) and the boiling point of the coolant remains unaffected.
Drive a little higher to where ambient pressure drops to 7 psi LESS than sea level (7.7 psi) and the cooling system pressure is still only 20 psi because the cap vented. HOWEVER, the absolute pressure has fallen by 2 psi (20 + 7.7 = 27.7 psi), and the boiling point of the coolant has decreased proportionally.
Drive the car back down to sea level and the cooling system pressure falls to 13 psi but the ABSOLUTE pressure and coolant boiling point remain the same as when the car was at its highest point (14.7 + 13 = 27.7 psi).
Now park the car, shut it off, and let it cool down over night. As it cools, the cooling system will develop a vacuum and draw air in through the rad cap (it allows air to pass under a vacuum situation). The next morning, start the car and operate it as usual at sea level, and the cooling system is back to normal, operating at the same 15 psi it was before.
We need not make this any more complicated...
