That will tell if you the TPMS is working or not, but I don't think you can use it to learn the rotation. You could in prior years. But later years requires the tool. But letting enough air out should trigger some indication.
I doubt that letting air out will do a thing.....those new sensors have new id#'s and the receiver will ignore any information they send.
If this was not the case, your car would read other car sensors sitting next to you.